2093935-86-3
2093935-86-3 structure
- Name: SLAP TA
- Chemical Name: SLAP TA
- CAS Number: 2093935-86-3
- Molecular Formula: C7H19NSSi
- Molecular Weight: 177.38
- Create Date: 2023-01-17 09:04:56
- Modify Date: 2024-04-06 16:15:42
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Description When used with aliphatic or aromatic aldehydes, this silicon amine protocolSLAP reagent enables the photomediated synthesis of thiomorpholines and thiazepanes. For photocatalytic cross-coupling with this SLAP Reagent, Ir[(ppy)2dtbbpy]PF6(747769) is used with a recommended starting combination of Lewis acids Bi(OTf)3(633305) and Cu(OTf)2(283673) prior to subsequent substrate-specific optimization. This product was introduced in collaboration with theBode Research Groupand provides a tin-free alternative toSnAP(tin amine protocol) reagents and is well-suited for scale-up reactions.
| Name | SLAP TA |
|---|---|
| Synonyms | 3-(((Trimethylsilyl)methyl)thio)propan-1-amine |
| Density | 0.90452 |
|---|---|
| Boiling Point | 218.2±25.0 °C at 760 mmHg |
| Molecular Formula | C7H19NSSi |
| Molecular Weight | 177.38 |
| Flash Point | 23.89 °C |
| Exact Mass | 177.100739 |
| LogP | 2.01 |
| Vapour Pressure | 0.1±0.4 mmHg at 25°C |
| Index of Refraction | 1.466 |
| RIDADR | UN1993C |
|---|---|
| Hazard Class | 3 |