D-Camphorsulfonic acid

Names

[ Name ]:
D-Camphorsulfonic acid

[Synonym ]:
10-Bornanesulfonic acid, 2-oxo-, (1S,4R)-(+)-
b-Camphorsulfonic Acid
UNII:D8D049375Q
D-CAMPHORSULFONIC ACID
(1S)-Camphor-10-sulfonic acid
D-(+)-10-Camphorsulfonic Acid
(+)-Camphor-w-sulfonic Acid
(+)-D-Camphor-10-sulfonic Acid
CSA
camphersulfosaeure
Camphorsulfonic acid
Camphostyl
(1S)-(+)-CAMPHOR-10-SULPHONIC ACIDCamphorSulfonic Acid
EINECS 221-554-1
D-Camphor-10-Sulfonic Acid
Bicyclo(2.2.1)heptane-1-methanesulfonic acid, 7,7-dimethyl-2-oxo-, (1S,4R)-
MFCD00064157
(1S)-(+)-10-Camphors
(+)-b-Camphorsulfonic Acid
(+)-(S)-Camphor-10-sulfonic Acid
(1S,4R)-(+)-2-Oxo-10-bornanesulfonic Acid
[(1S,4R)-7,7-Dimethyl-2-oxobicyclo[2.2.1]hept-1-yl]methanesulfonic acid
((1S,4R)-7,7-Dimethyl-2-oxobicyclo-[2.2.1]heptan-1-yl)methanesulfonic acid
(1S,4R)-7,7-Dimethyl-2-oxobicyclo[2.2.1]heptane-1-methanesulfonic Acid
(1S)-(+)-CSA
D-CAMPHORSULPHONIC ACID
D(+)-10-Camphorsulfonic acid
(S)-10-camphorsulphonic acid
D-10-CAMPHORSULFONIC ACID
10-Camphorsulfonic acid
Bicyclo[2.2.1]heptane-1-methanesulfonic acid, 7,7-dimethyl-2-oxo-, (1S,4R)-
((1S,4R)-7,7-Dimethyl-2-oxobicyclo[2.2.1]heptan-1-yl)methanesulfonic acid
Reychler's acid
(+)-10-Camphorsulfonic Acid
(+)-Camphor-10-sulfonic acid (β)
(+)-camphorsulfonicacid
D-REYCHLER'S ACID
(1S)-(+)-10-Camphorsulfonic acid

Chemical & Physical Properties

[ Density]:
1.3±0.1 g/cm3

[ Melting Point ]:
195ºC

[ Molecular Formula ]:
C₁₀H₁₆O₄S

[ Molecular Weight ]:
232.297

[ Exact Mass ]:
232.076935

[ PSA ]:
79.82000

[ LogP ]:
-0.57

[ Index of Refraction ]:
1.540

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :: ED1550000

CHEMICAL NAME :: 10-Bornanesulfonic acid, 2-oxo-, (1S,4R)-(+)-

CAS REGISTRY NUMBER :: 3144-16-9

LAST UPDATED :: 199701

DATA ITEMS CITED :: 2

MOLECULAR FORMULA :: C10-H16-O4-S

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Subcutaneous

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 2502 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: PHARAT Pharmazie. (VEB Verlag Volk und Gesundheit, Neue Gruenstr. 18, Berlin DDR-1020, Ger. Dem. Rep.) V.1- 1946- Volume(issue)/page/year: 1,150,1946

Safety Information

[ Symbol ]:

GHS05

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H314

[ Precautionary Statements ]:
P260-P280-P303 + P361 + P353-P304 + P340 + P310-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges

[ Hazard Codes ]:
C:Corrosive

[ Risk Phrases ]:
R34

[ Safety Phrases ]:
S25-S36/37/39-S45

[ RIDADR ]:
UN 3261 8/PG 2

[ WGK Germany ]:
3

[ RTECS ]:
ED1550000

[ Packaging Group ]:
III

[ Hazard Class ]:
8.0

[ HS Code ]:
29147090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

DownStream

Customs

[ HS Code ]: 2914299000

[ Summary ]:
2914299000. other cyclanic, cyclenic or cyclotherpenic ketones without other oxygen function. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:5.5%. General tariff:30.0%

Articles

Salt Stability - The Effect of pHmax on Salt to Free Base Conversion.

Pharm. Res. 32 , 3110-8, (2015)

The aim of this study was to investigate how the disproportionation process can be impacted by the properties of the salt, specifically pHmax.Five miconazole salts and four sertraline salts were selec...

Analysis of deprotonated acids with silicon nanoparticle-assisted laser desorption/ ionization mass spectrometry.

J. Mass Spectrom. 45(12) , 1394-401, (2010)

Chemically modified silicon nanoparticles were applied for the laser desorption/negative ionization of small acids. A series of substituted sulfonic acids and fatty acids was studied. Compared to deso...

Camphorsulfonic acid catalysed facile tandem double Friedlander annulation protocol for the synthesis of phenoxy linked bisquinoline derivatives and discovery of antitubercular agents.

Bioorg. Med. Chem. Lett. 22 , 1643-8, (2012)

A series of phenoxy linked bisquinoline derivatives were synthesised from the Friedlander annulation of 2-(4-acetylphenoxy)-1-aryl-1-ethanones with 2-aminobenzophenone in good yields using (±)-camphor...