Acetoacet-o-toluidide

Names

[ CAS No. ]:
93-68-5

[ Name ]:
Acetoacet-o-toluidide

[Synonym ]:
acetoacetamino-2-methylbenzene
Acetoacet-O-toludide
EINECS 202-267-0
3-Oxo-N-(2,4-methylphenyl)butanamide
2'-Methylacetoacetanilide
N-(2-Methylphenyl)-3-oxobutanamide
O-Acetoacetoluidide
acetoacetyl o-methylaniline
O-ACETOACETOTOLUIDIDE
ACETO ACET O TOLUIDINE
1V1VMR B1
Butanamide, N-(2-methylphenyl)-3-oxo-
N-(2-methylphenyl)acetoacetamide
2'-acetoacetoluidide
2'-Methylacetoacetan
2'-METHYL-3-PHENYLPROPIOPHENONE
2-acetyl-6-methylacetanilide
N-(o-tolyl)acetoacetic amide
Acetoacet-o-toluidide
AAOT
2-ACETOACETOTOLUIDIDE
MFCD00008782
AcetoAcet-O-Toluilide

Chemical & Physical Properties

[ Density]:
1.1±0.1 g/cm3

[ Boiling Point ]:
360.6±25.0 °C at 760 mmHg

[ Melting Point ]:
104-106 °C(lit.)

[ Molecular Formula ]:
C₁₁H₁₃NO₂

[ Molecular Weight ]:
191.226

[ Flash Point ]:
143.3±0.0 °C

[ Exact Mass ]:
191.094635

[ PSA ]:
46.17000

[ LogP ]:
1.31

[ Vapour Pressure ]:
0.0±0.8 mmHg at 25°C

[ Index of Refraction ]:
1.560

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :: AK6550000

CHEMICAL NAME :: o-Acetoacetotoluidide

CAS REGISTRY NUMBER :: 93-68-5

BEILSTEIN REFERENCE NO. :: 2099098

LAST UPDATED :: 199701

DATA ITEMS CITED :: 4

MOLECULAR FORMULA :: C11-H13-N-O2

MOLECULAR WEIGHT :: 191.25

WISWESSER LINE NOTATION :: 1V1VMR B

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 1600 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: KODAK* Kodak Company Reports. (343 State St., Rochester, NY 14650) Volume(issue)/page/year: GN-229B,1983

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 1600 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: KODAK* Kodak Company Reports. (343 State St., Rochester, NY 14650) Volume(issue)/page/year: GN-229B,1983

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - guinea pig

DOSE/DURATION :: >1 gm/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: KODAK* Kodak Company Reports. (343 State St., Rochester, NY 14650) Volume(issue)/page/year: GN-229B,1983

Safety Information

[ Hazard Codes ]:
Xn:Harmful;

[ Risk Phrases ]:
R22

[ Safety Phrases ]:
S36

[ WGK Germany ]:
1

[ RTECS ]:
AK6550000

[ HS Code ]:
2924299090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

DownStream

Customs

[ HS Code ]: 2924299090

[ Summary ]:
2924299090. other cyclic amides (including cyclic carbamates) and their derivatives; salts thereof. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%