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2-bromo-4'-methylacetophenone

Names

[ CAS No. ]:
619-41-0

[ Name ]:
2-bromo-4'-methylacetophenone

[Synonym ]:
Ethanone, 2-bromo-1-(4-methylphenyl)-
2-bromo-4'-methylacetophenone
EINECS 226-267-5
2-Bromo-1-(4-methylphenyl)ethanone
MFCD00009312
Acetophenone, 2-bromo-4'-methyl-

Chemical & Physical Properties

[ Density]:
1.4±0.1 g/cm3

[ Boiling Point ]:
263.6±15.0 °C at 760 mmHg

[ Melting Point ]:
45-49 °C(lit.)

[ Molecular Formula ]:
C9H9BrO

[ Molecular Weight ]:
213.071

[ Flash Point ]:
74.4±7.7 °C

[ Exact Mass ]:
211.983673

[ PSA ]:
17.07000

[ LogP ]:
2.65

[ Vapour Pressure ]:
0.0±0.5 mmHg at 25°C

[ Index of Refraction ]:
1.563

[ Storage condition ]:
-20?C Freezer, Under Inert Atmosphere

[ Stability ]:
Stable. Incompatible with strong oxidizing agents, strong bases.

MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi:Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S27-S37/39

[ RIDADR ]:
UN 2811

[ WGK Germany ]:
3

[ Hazard Class ]:
6.1

[ HS Code ]:
2914700090

Synthetic Route

Precursor & DownStream

Customs

[ HS Code ]: 2914700090

[ Summary ]:
HS: 2914700090 halogenated, sulphonated, nitrated or nitrosated derivatives of ketones and quinones, whether or not with other oxygen function Tax rebate rate:9.0% Supervision conditions:none VAT:17.0% MFN tariff:5.5% General tariff:30.0%

Articles

Efficient solid-phase synthesis of 2-substituted-3-hydroxy-4(1H)-quinolinone-7-carboxamides with two diversity positions.

J. Comb. Chem. 9(5) , 793-6, (2007)

A highly efficient solid-phase synthesis of 2-substituted-3-hydroxy-4(1H)-quinolinone-7-carboxamides was developed using anthranilates and bromoketones as the key synthons. Primary amines immobilized ...

Use of fluorous silica gel to separate fluorous thiol quenching derivatives in solution-phase parallel synthesis Zhang W, et al.

Tetrahedron 58(20) , 3871-75, (2002)


More Articles


Related Compounds

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