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2-Acetylcyclohexanone

Names

[ CAS No. ]:
874-23-7

[ Name ]:
2-Acetylcyclohexanone

[Synonym ]:
2-Acetylcyclohexanone
2-acetylcyclohexanone for synthesis
2-Acetyl-1-cyclohexanone
2-acetylcyclohexa
2-acetyl cyclohexanone
Cyclohexanone, 2-acetyl-
MFCD00001633
EINECS 212-858-5
cyclohexanone,2-acetyl-
2-acetylcyclohexanon

Chemical & Physical Properties

[ Density]:
1.0±0.1 g/cm3

[ Boiling Point ]:
224.3±0.0 °C at 760 mmHg

[ Molecular Formula ]:
C8H12O2

[ Molecular Weight ]:
140.180

[ Flash Point ]:
79.4±0.0 °C

[ Exact Mass ]:
140.083725

[ PSA ]:
34.14000

[ LogP ]:
0.08

[ Vapour Pressure ]:
0.1±0.4 mmHg at 25°C

[ Index of Refraction ]:
1.464

MSDS

Safety Information

[ Personal Protective Equipment ]:
Eyeshields;Gloves;half-mask respirator (US);multi-purpose combination respirator cartridge (US)

[ Safety Phrases ]:
S23-S24/25

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ HS Code ]:
2914299000

Synthetic Route

Precursor & DownStream

Customs

[ HS Code ]: 2914299000

[ Summary ]:
2914299000. other cyclanic, cyclenic or cyclotherpenic ketones without other oxygen function. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:5.5%. General tariff:30.0%

Articles

Tautomerization of 2-acetylcyclohexanone. 1. Characterization of keto-enol/enolate equilibria and reaction rates in water.

J. Org. Chem. 68(7) , 2680-8, (2003)

The keto-enol tautomerism of 2-acetylcyclohexanone (ACHE) was studied in water under different experimental conditions. By contrast with other previously studied beta-diketones, the keto-enol intercon...

Copper-catalyzed amination of (bromophenyl)ethanolamine for a concise synthesis of aniline-containing analogues of NMDA NR2B antagonist ifenprodil.

Org. Biomol. Chem. 8(5) , 1111-20, (2010)

An operationally simple and concise synthesis of anilinoethanolamines, as NMDA NR2B receptor antagonist ifenprodil analogues, was developed via a copper-catalyzed amination of the corresponding bromoa...

An alternative to the classical α-arylation: the transfer of an intact 2-iodoaryl from ArI(O₂CCF₃)₂.

Angew. Chem. Int. Ed. Engl. 53(42) , 11298-301, (2014)

The α-arylation of carbonyl compounds is generally accomplished under basic conditions, both under metal catalysis and via aryl transfer from the diaryl λ(3)-iodanes. Here, we describe an alternative ...


More Articles


Related Compounds