Triethyl phosphonoacetate
Names
[ CAS No. ]:
867-13-0
[ Name ]:
Triethyl phosphonoacetate
[Synonym ]:
EINECS 212-757-6
Triethyl phosphonacetate
Triethyl phosphonoac
Triethyl phosphono acetate
(ETHOXYCARBONYLMETHYL)DIETHOXYPHOSPHINEOXIDE
AURORA KA-1452
diethyl ethoxycarbonylmethanephosphonate
Ethyl (diethoxyphosphoryl)acetate
ethyl diethoxyphosphorylacetate
MFCD00009177
PHOSPHONOACETIC ACID ETHYL ESTER
(ETHOXYCARBONYLMETHYL)-DIETHOXYPHOSPHINE OXIDE
TRIETHYL PHOSPHONACETIC ACID
diethoxyphosphoryl-acetic acid ethyl ester
TRIETHYLPHOSPHONEACETATE
TRIETHYLPHOSPHONOAETATE
Triethylphosphonoacetate
TRENBOLONE HEXAHYDROBENZYL CARBONATE
Acetic acid, 2-(diethoxyphosphinyl)-, ethyl ester
TRIETHYL PHOSPHONOACEATE
ethyl 2-(diethoxyphosphoryl)acetate
tl465
Triethyl Phosphonoacetate ( Tepp)
TRIETHYL PHOSPHONOACETATE FOR SYNTHESIS
Triethyl phosphonoacetate
TRIETHYLPHOSPONOACETATE
Diethylphosphonoacetic Acid Ethyl Ester
Trietyl Phosphonoacetate
phosphonoacetic acid triethyl ester
Diethyl [(ethoxycarbonyl)methyl]phosphonate
Biological Activity
[Description]:
[Related Catalog]:
[In Vitro]
Chemical & Physical Properties
[ Density]:
1.1±0.1 g/cm3
[ Boiling Point ]:
287.4±23.0 °C at 760 mmHg
[ Melting Point ]:
-24°C
[ Molecular Formula ]:
C8H17O5P
[ Molecular Weight ]:
224.19
[ Flash Point ]:
141.6±42.9 °C
[ Exact Mass ]:
224.081360
[ PSA ]:
71.64000
[ LogP ]:
0.92
[ Vapour Pressure ]:
0.0±0.6 mmHg at 25°C
[ Index of Refraction ]:
1.424
[ Storage condition ]:
Refrigerator
MSDS
Toxicological Information
CHEMICAL IDENTIFICATION
- RTECS NUMBER :
- AG9800000
- CHEMICAL NAME :
- Acetic acid, diethylphosphono-, ethyl ester
- CAS REGISTRY NUMBER :
- 867-13-0
- LAST UPDATED :
- 199701
- DATA ITEMS CITED :
- 3
- MOLECULAR FORMULA :
- C8-H17-O5-P
- MOLECULAR WEIGHT :
- 224.22
- WISWESSER LINE NOTATION :
- OPO&O&2&2&1VO2
HEALTH HAZARD DATA
ACUTE TOXICITY DATA
- TYPE OF TEST :
- LD - Lethal dose
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- >500 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- NCNSA6 National Academy of Sciences, National Research Council, Chemical-Biological Coordination Center, Review. (Washington, DC) Volume(issue)/page/year: 5,15,1953
- TYPE OF TEST :
- LCLo - Lowest published lethal concentration
- ROUTE OF EXPOSURE :
- Inhalation
- SPECIES OBSERVED :
- Rodent - mouse
- DOSE/DURATION :
- 1180 mg/m3/10M
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- NDRC** National Defense Research Committee, Office of Scientific Research and Development, Progress Report. Volume(issue)/page/year: NDCrc-132,NOV1942
Safety Information
[ Personal Protective Equipment ]:
Eyeshields;Gloves
[ Hazard Codes ]:
Xi:Irritant;
[ Risk Phrases ]:
R36/37/38;R51/53
[ Safety Phrases ]:
S61-S37/39-S26
[ RIDADR ]:
UN 3082 9/PG 3
[ WGK Germany ]:
3
[ RTECS ]:
AG9800000
[ Hazard Class ]:
9.0
[ HS Code ]:
2931901990
Synthetic Route
Precursor & DownStream
Precursor
DownStream
Customs
[ HS Code ]: 2931900090
[ Summary ]:
2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%
Articles
Int. J. Pept. Protein Res. 39(3) , 273-7, (1992)
Racemic "carba" pseudo-dipeptide units such as Gly-psi(CH2-CH2)-D,L-Xaa were obtained either through the Horner-Emmons condensation of N-tert.-butyloxycarbonyl-beta alaninal with the appropriate subst...
J. Boutagy, R. ThomasChem. Rev. 74 , 87, (1974)
T. Minami, J. Motoyoshiya
Synthesis , 333, (1991)