Boc-L- Prolinal

Names

[ Name ]:
Boc-L- Prolinal

[Synonym ]:
1-Pyrrolidinecarboxylic acid, 2-formyl-, 1,1-dimethylethyl ester, (2S)-
tert-butyl (2S)-2-formylpyrrolidine-1-carboxylate
(S)-1-Boc-2-Formylpyrrolidine
MFCD00274186
(S)-(-)-1-Boc-pyrrolidine-2-carboxaldehyde
Boc-L- Prolinal
(S)-N-(TERT-BUTOXYCARBONYL)PROLINAL
2-Methyl-2-propanyl (2S)-2-formyl-1-pyrrolidinecarboxylate
N-BOC-L-Prolinal

Chemical & Physical Properties

[ Density]:
1.1±0.1 g/cm3

[ Boiling Point ]:
276.3±33.0 °C at 760 mmHg

[ Molecular Formula ]:
C₁₀H₁₇NO₃

[ Molecular Weight ]:
199.247

[ Flash Point ]:
120.9±25.4 °C

[ Exact Mass ]:
199.120850

[ PSA ]:
46.61000

[ LogP ]:
0.69

[ Vapour Pressure ]:
0.0±0.6 mmHg at 25°C

[ Index of Refraction ]:
1.528

[ Storage condition ]:
-20°C

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS02, GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H226-H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xi:Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S36

[ RIDADR ]:
UN 1989C 3 / PGIII

[ WGK Germany ]:
3

[ HS Code ]:
2933990090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

DownStream

Customs

[ HS Code ]: 2933990090

[ Summary ]:
2933990090. heterocyclic compounds with nitrogen hetero-atom(s) only. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

Articles

A new general access to either type of Securinega alkaloids: synthesis of securinine and (-)-allonorsecurinine.

Org. Lett. 6 , 1813, (2004)

The syntheses of securinine and (-)-allonorsecurinine have been achieved starting from easily available alpha-amino acid derivatives and using as key steps a RCM and a Heck reaction for the formation ...

Tetrahedron Lett. 45 , 2985, (2004)