Methyl 2-methoxybenzoate
Names
[ CAS No. ]:
606-45-1
[ Name ]:
Methyl 2-methoxybenzoate
[Synonym ]:
Methyol o-methoxybenzoate
Methyl o-anisate
dimethyl salicylate
methyl methoxybenzoate
Methyl o-methoxybenzoate
methoxy-benzoic acid methyl ester
2-Methoxybenzoic Acid Methyl Ester
BENZOIC ACID,2-METHOXY-,METHYL ESTER
methyl monomethoxybenzoate
o-Methoxybenzoic acid methyl ester
Benzoic acid, 2-methoxy-, methyl ester
Methyl 2-methoxybenzoate
o-Anisic acid,methyl ester
EINECS 210-118-6
MFCD00008423
Chemical & Physical Properties
[ Density]:
1.1±0.1 g/cm3
[ Boiling Point ]:
245.0±0.0 °C at 760 mmHg
[ Molecular Formula ]:
C9H10O3
[ Molecular Weight ]:
166.174
[ Flash Point ]:
93.8±14.4 °C
[ Exact Mass ]:
166.062988
[ PSA ]:
35.53000
[ LogP ]:
2.04
[ Vapour Pressure ]:
0.0±0.5 mmHg at 25°C
[ Index of Refraction ]:
1.503
MSDS
Toxicological Information
CHEMICAL IDENTIFICATION
- RTECS NUMBER :
- DH3549000
- CHEMICAL NAME :
- Benzoic acid, 2-methoxy-, methyl ester
- CAS REGISTRY NUMBER :
- 606-45-1
- BEILSTEIN REFERENCE NO. :
- 2207356
- LAST UPDATED :
- 199701
- DATA ITEMS CITED :
- 3
- MOLECULAR FORMULA :
- C9-H10-O3
HEALTH HAZARD DATA
ACUTE TOXICITY DATA
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 3800 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- FCTOD7 Food and Chemical Toxicology. (Pergamon Press Inc., Maxwell House, Fairview Park, Elmsford, NY 10523) V.20- 1982- Volume(issue)/page/year: 26,385,1988
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Administration onto the skin
- SPECIES OBSERVED :
- Rodent - rabbit
- DOSE/DURATION :
- >5 gm/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- FCTOD7 Food and Chemical Toxicology. (Pergamon Press Inc., Maxwell House, Fairview Park, Elmsford, NY 10523) V.20- 1982- Volume(issue)/page/year: 26,385,1988
Safety Information
[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves
[ Hazard Codes ]:
Xi:Irritant;
[ Risk Phrases ]:
R36/37/38
[ Safety Phrases ]:
S26-S36-S37/39
[ RIDADR ]:
NONH for all modes of transport
[ WGK Germany ]:
2
[ RTECS ]:
DH3549000
[ HS Code ]:
29189090
Synthetic Route
Precursor & DownStream
Precursor
DownStream
Customs
[ HS Code ]: 2918990090
[ Summary ]:
2918990090. other carboxylic acids with additional oxygen function and their anhydrides, halides, peroxides and peroxyacids; their halogenated, sulphonated, nitrated or nitrosated derivatives. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%
Articles
Angew. Chem. Int. Ed. Engl. 48(21) , 3817-20, (2009)
Hooking up: FeCl(2) catalyzes the efficient cross dehydrogenative arylation of substrates having benzylic C-H bonds (see scheme). High regioselectivity was observed during the cross-coupling between c...
Synthesis of (+/-)-vibralactone.Org. Lett. 10(7) , 1401-4, (2008)
Reductive alkylation of methyl 2-methoxybenzoate with prenyl bromide and hydrolysis afforded methyl 6-oxo-1-prenyl-2-cyclohexenecarboxylate. Reduction of the ketone, hydrolysis, iodolactonization, ozo...