Chloromethyl chlorosulfate
Names
[ CAS No. ]:
49715-04-0
[ Name ]:
Chloromethyl chlorosulfate
[Synonym ]:
Chlorosulfuric acid, chloromethyl ester
Chlorosulfuric acid (HSO), chloromethyl ester
EINECS 256-442-1
Chloromethyl chlorosulphate
chloro(chlorosulfonyloxy)methane
Chlorosulfuric Acid Chloromethyl Ester
MFCD00041547
Chloromethyl chlorosulfate
Chloromethyl sulfurochloridate
Chlorosulfonic Acid Chloromethyl Ester
ChloroMethyl Chlorosulfonate
Chemical & Physical Properties
[ Density]:
1.7±0.1 g/cm3
[ Boiling Point ]:
192.6±23.0 °C at 760 mmHg
[ Molecular Formula ]:
CH2Cl2O3S
[ Molecular Weight ]:
164.996
[ Flash Point ]:
70.3±22.6 °C
[ Exact Mass ]:
163.910172
[ PSA ]:
51.75000
[ LogP ]:
0.92
[ Vapour Pressure ]:
0.7±0.4 mmHg at 25°C
[ Index of Refraction ]:
1.477
[ Storage condition ]:
Store at 2-8C
[ Water Solubility ]:
reacts
MSDS
Safety Information
[ Symbol ]:
GHS05, GHS06, GHS08
[ Signal Word ]:
Danger
[ Hazard Statements ]:
H302-H314-H330-H350
[ Precautionary Statements ]:
P201-P260-P280-P304 + P340 + P310-P305 + P351 + P338-P308 + P313
[ Personal Protective Equipment ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
[ Hazard Codes ]:
T+:Verytoxic;C:Corrosive;
[ Risk Phrases ]:
R22;R26;R34
[ Safety Phrases ]:
S26-S36/37/39-S45-S28A
[ RIDADR ]:
UN 1760 8/PG 3
[ WGK Germany ]:
3
[ Packaging Group ]:
I; II
[ Hazard Class ]:
6.1
Synthetic Route
Precursor & DownStream
Precursor
DownStream
Articles
Org. Biomol. Chem. 2 , 1554, (2004)
The reaction of liquid (gamma-) SO3 with CH2Cl2 at room temperature leads to SO3 insertion into the C-Cl bonds, giving the useful chloromethylating agent chloromethyl chlorosulfate (CMCS). The process...