diethoxymethane
Names
[ CAS No. ]:
462-95-3
[ Name ]:
diethoxymethane
[Synonym ]:
Formaldehyde Diethyl Acetal
diethoxy methane
diethoxymethane
Methylene Glycol Diethyl Ether
EINECS 207-330-6
Formaldehyde, diethyl acetal
(Ethoxymethoxy)ethane
Ethane, 1,1'-[methylenebis(oxy)]bis-
ethoxymethoxyethane
MFCD00009246
Diethylformal
Chemical & Physical Properties
[ Density]:
0.8±0.1 g/cm3
[ Boiling Point ]:
89.0±0.0 °C at 760 mmHg
[ Melting Point ]:
-66.5 °C
[ Molecular Formula ]:
C5H12O2
[ Molecular Weight ]:
104.148
[ Flash Point ]:
-5.6±0.0 °C
[ Exact Mass ]:
104.083733
[ PSA ]:
18.46000
[ LogP ]:
0.80
[ Vapour density ]:
3.6 (vs air)
[ Vapour Pressure ]:
67.3±0.1 mmHg at 25°C
[ Index of Refraction ]:
1.380
[ Stability ]:
Stable. Highly flammable. Incompatible with strong oxidizing agents, strong acids.
[ Water Solubility ]:
4.2 G/100 ML
MSDS
Toxicological Information
CHEMICAL IDENTIFICATION
- RTECS NUMBER :
- PA8500000
- CHEMICAL NAME :
- Methane, diethoxy-
- CAS REGISTRY NUMBER :
- 462-95-3
- BEILSTEIN REFERENCE NO. :
- 1697253
- LAST UPDATED :
- 199709
- DATA ITEMS CITED :
- 3
- MOLECULAR FORMULA :
- C5-H12-O2
- MOLECULAR WEIGHT :
- 104.17
- WISWESSER LINE NOTATION :
- 2O1O2
HEALTH HAZARD DATA
ACUTE TOXICITY DATA
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - rabbit
- DOSE/DURATION :
- 2604 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- PSEBAA Proceedings of the Society for Experimental Biology and Medicine. (Academic Press, Inc., 1 E. First St., Duluth, MN 55802) V.1- 1903/04- Volume(issue)/page/year: 29,730,1932 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - 84039 No. of Facilities: 5 (estimated) No. of Industries: 1 No. of Occupations: 2 No. of Employees: 20 (estimated)
Safety Information
[ Symbol ]:
GHS02, GHS07
[ Signal Word ]:
Danger
[ Hazard Statements ]:
H225-H315-H319-H335
[ Precautionary Statements ]:
P210-P261-P305 + P351 + P338
[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
[ Hazard Codes ]:
F:Flammable;Xi:Irritant;
[ Risk Phrases ]:
R11;R36/37/38
[ Safety Phrases ]:
S16-S26-S36
[ RIDADR ]:
UN 2373 3/PG 2
[ WGK Germany ]:
2
[ RTECS ]:
PA8500000
[ Packaging Group ]:
II
[ Hazard Class ]:
3
[ HS Code ]:
2909199090
Synthetic Route
Precursor & DownStream
Precursor
DownStream
Customs
[ HS Code ]: 2909199090
[ Summary ]:
2909199090. other acyclic ethers and their halogenated, sulphonated, nitrated or nitrosated derivatives. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:5.5%. General tariff:30.0%
Articles
J. Proteomics 128 , 18-29, (2015)
Cellular senescence causes profound changes in gene expression profile. In this study, we used a combined 2D-DIGE and nanoLC-ESI-LIT-MS/MS approach to evaluate the proteomic changes occurring both in ...
Designing greener plasticizers: Effects of alkyl chain length and branching on the biodegradation of maleate based plasticizers.Chemosphere 134 , 106-12, (2015)
The ubiquitous presence of the plasticizer di (2-ethylhexyl) phthalate (DEHP) in the environment is of concern due to negative biological effects associated with it and its metabolites. In particular,...
A novel toxicogenomics-based approach to categorize (non-)genotoxic carcinogens.Arch. Toxicol. 89 , 2413-27, (2015)
Alternative methods to detect non-genotoxic carcinogens are urgently needed, as this class of carcinogens goes undetected in the current testing strategy for carcinogenicity under REACH. A complicatin...