Diphenyl-2-pyridylphosphine

Names

[ Name ]:
Diphenyl-2-pyridylphosphine

[Synonym ]:
2-(Diphenylphosphino)pyridine 2-Pyridyldiphenylphosphine Diphenyl(2-pyridinyl)phosphine
MFCD00192108
Pyridine, 2-(diphenylphosphino)-
2-diphenylphosphinopyridine
diphenyl(pyridin-2-yl)phosphane
2-diphenylphosphanyl-pyridine
2-pyridyldiphenylphosphine
Diphenyl-2-pyridylphosphine
2-(Diphenylphosphino)pyridine

Biological Activity

[Description]:

Diphenyl-2-pyridylphosphine is a biochemical reagent that can be used as a biological material or organic compound for life science related research.

[Related Catalog]:

Research Areas >> Others

[In Vitro]

它是金属催化的羰基化、水合、脱氢偶联、碳甲锡烷基化、二甲锡烷基化和甲硅烷基化的配体。也用作光延反应的试剂。

Chemical & Physical Properties

[ Boiling Point ]:
377.5±15.0 °C at 760 mmHg

[ Melting Point ]:
82-84 °C (dec.)(lit.)

[ Molecular Formula ]:
C₁₇H₁₄NP

[ Molecular Weight ]:
263.28

[ Flash Point ]:
182.1±20.4 °C

[ Exact Mass ]:
263.086395

[ PSA ]:
26.48000

[ LogP ]:
4.20

[ Vapour Pressure ]:
0.0±0.8 mmHg at 25°C

[ Storage condition ]:
Refrigerator

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335-H413

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi:Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S36

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ HS Code ]:
2933399090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

DownStream

Customs

[ HS Code ]: 2933399090

[ Summary ]:
2933399090. other compounds containing an unfused pyridine ring (whether or not hydrogenated) in the structure. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

Articles

Nickel-catalyzed tandem carbostannylation of alkynes and 1,2-dienes with alkynylstannanes.

Angew. Chem. Int. Ed. Engl. 43 , 3448, (2004)

Palladium-catalyzed distannylation of ortho-quinodimethanes.

Org. Lett. 8 , 4157, (2006)

An exo-diene moiety of various ortho-quinodimethanes, regardless of its transient character, was inserted into a Sn-Sn sigma-bond of hexabutyldistannane in the presence of a palladium catalyst, giving...

Consorti, C. S.; Ebeling, G.; Dupont, J.

Tetrahedron Lett. 43 , 753, (2002)

Related Compounds

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