Chlorodiphenylphosphine

Names

[ Name ]:
Chlorodiphenylphosphine

[Synonym ]:
MFCD00000529
diphenylphosphine chloride
(C6H5)2PCl
chloro-diphenylphosphine
Diphenylphosphinous chloride
Phosphine,chlorodiphenyl
Diphenylphosphinchlorid
PH2PCL
Phosphinous chloride, P,P-diphenyl-
P-CHLORODIPHENYLPHOSPHINE
Phosphinous chloride, diphenyl-
DIPHENYLCHLOROPHOSPHINE
Chlorodiphenylphosphine
diphenylphosphinyl chloride
diphenylphosphoryl chloride
CHLORODIPHENYLPHOSPINE
Phosphine, chlorodiphenyl-
AURORA KA-1322
EINECS 214-093-2

Chemical & Physical Properties

[ Density]:
1.229 g/mL at 25 °C(lit.)

[ Boiling Point ]:
320.0±11.0 °C at 760 mmHg

[ Melting Point ]:
14-16°C

[ Molecular Formula ]:
C₁₂H₁₀ClP

[ Molecular Weight ]:
220.635

[ Flash Point ]:
147.3±19.3 °C

[ Exact Mass ]:
220.020859

[ PSA ]:
13.59000

[ LogP ]:
5.33

[ Vapour density ]:
7.8 (vs air)

[ Vapour Pressure ]:
0.0±0.7 mmHg at 25°C

[ Index of Refraction ]:
n20/D 1.636(lit.)

[ Storage condition ]:
Store at R.T.

[ Water Solubility ]:
Reacts violently

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS05

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H314

[ Supplemental HS ]:
Reacts violently with water.

[ Precautionary Statements ]:
P280-P305 + P351 + P338-P310

[ Personal Protective Equipment ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
C:Corrosive

[ Risk Phrases ]:
R14;R29;R34

[ Safety Phrases ]:
S26-S36/37/39-S45-S8-S30-S25

[ RIDADR ]:
UN 3265 8/PG 2

[ WGK Germany ]:
2

[ Packaging Group ]:
II

[ Hazard Class ]:
8

[ HS Code ]:
29310095

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

DownStream

Customs

[ HS Code ]: 2931900090

[ Summary ]:
2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%

Articles

Lewis acidity enhancement of triarylborane by appended phosphine oxide groups.

Dalton Trans. 44(10) , 4765-72, (2015)

A series of mono-, di-, and tri-phosphine oxide substituted triarylboranes, Mes2BAr (1), MesBAr2 (2), and BAr3 (3) (Ar = 4-(Ph2PO)-2,6-Me2-C6H2) were prepared to investigate the effect of a phosphine ...

J. Chem. Soc. Perkin Trans. I , 1433, 2463, (1993)

Chem. Pharm. Bull. 41 , 1149, (1993)