(Diacetoxyiodo)benzene
Names
[ CAS No. ]:
3240-34-4
[ Name ]:
(Diacetoxyiodo)benzene
[Synonym ]:
Iodosobenzene diacetate
bis-acetoxy iodobenzene
Phenyliodo diacetate
iodosobensene I,I-diacetate
Iodobenzene diacetate
Diacetoxy(phenyl)-λ-iodane
Iodine, bis(acetyloxy)phenyl-
phenyliodonium diacetate
Phenyliodine diacetate
iodobenzene 1,1-diacetate
EINECS 221-808-1
Iodobenzenediacetate
Phenyliodoso acetate
phenyliodine(iii) diacetate
Benzene, (diacetoxyiodo)-
iodosobenzene 1,1-diacetate
Phenyliodosodiacetate
MFCD00008692
(Diacetoxyiodo)benzene
bis(acetyloxy)(phenyl)-λ-iodane
Chemical & Physical Properties
[ Density]:
1.6865
[ Boiling Point ]:
456.8ºC at 760 mmHg
[ Melting Point ]:
161-165 ºC
[ Molecular Formula ]:
C10H11IO4
[ Molecular Weight ]:
322.096
[ Flash Point ]:
230.1ºC
[ Exact Mass ]:
321.970184
[ PSA ]:
52.60000
[ LogP ]:
2.31880
[ Storage condition ]:
-20°C
[ Water Solubility ]:
INSOLUBLE
MSDS
Toxicological Information
CHEMICAL IDENTIFICATION
- RTECS NUMBER :
- DA3525000
- CHEMICAL NAME :
- Benzene, iodoso-, diacetate
- CAS REGISTRY NUMBER :
- 3240-34-4
- LAST UPDATED :
- 199712
- DATA ITEMS CITED :
- 2
- MOLECULAR FORMULA :
- C10-H11-I-O4
- MOLECULAR WEIGHT :
- 322.11
- WISWESSER LINE NOTATION :
- 1VO-I-R &OV1 &5/10
HEALTH HAZARD DATA
ACUTE TOXICITY DATA
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Intravenous
- SPECIES OBSERVED :
- Rodent - mouse
- DOSE/DURATION :
- 56 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. (Aberdeen Proving Ground, MD 21010) Volume(issue)/page/year: NX#02976
Safety Information
[ Personal Protective Equipment ]:
Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter
[ Hazard Codes ]:
Xi:Irritant
[ Risk Phrases ]:
R36/37/38
[ Safety Phrases ]:
S22-S24/25-S37/39-S26
[ RIDADR ]:
1479
[ WGK Germany ]:
3
[ RTECS ]:
DA3525000
[ Packaging Group ]:
III
[ Hazard Class ]:
6.1(b)
[ HS Code ]:
29310095
Synthetic Route
Precursor & DownStream
Precursor
DownStream
Customs
[ HS Code ]: 2916399090
[ Summary ]:
2916399090 other aromatic monocarboxylic acids, their anhydrides, halides, peroxides, peroxyacids and their derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%
Articles
Org. Lett. 12(7) , 1552-5, (2010)
PhI(OAc)(2) in the presence of OsO(4) (cat.) and 2,6-lutidine cleaves olefinic bonds to yield the corresponding carbonyl compounds, albeit, in some cases, with alpha-hydroxy ketones as byproduct. A mo...
Palladium-catalyzed oxygenation of unactivated sp3 C-H bonds.J. Am. Chem. Soc. 126 , 9542-9543, (2004)
This communication describes a new palladium-catalyzed method for the oxygenation of unactivated sp3 C-H bonds. A wide variety of alkane substrates containing readily available oxime and/or pyridine d...
Determination of vitamin C in tablets and fruits by titration with phenyliodosoacetate.Il Farmaco 37(1) , 9-14, (1982)