2(3H)-Furanone,3-bromodihydro-5-methyl-
Names
[ CAS No. ]:
25966-39-6
[ Name ]:
2(3H)-Furanone,3-bromodihydro-5-methyl-
[Synonym ]:
EINECS 247-380-6
2-bromo-2-methylbutyrolactone
MFCD00005388
Chemical & Physical Properties
[ Density]:
1.618g/cm3
[ Boiling Point ]:
254.1ºC at 760mmHg
[ Molecular Formula ]:
C5H7BrO2
[ Molecular Weight ]:
179.01200
[ Flash Point ]:
107.5ºC
[ Exact Mass ]:
177.96300
[ PSA ]:
26.30000
[ LogP ]:
1.08530
[ Vapour Pressure ]:
0.0175mmHg at 25°C
[ Index of Refraction ]:
n20/D 1.493(lit.)
MSDS
Safety Information
[ Symbol ]:
GHS05, GHS07
[ Signal Word ]:
Danger
[ Hazard Statements ]:
H314-H335
[ Precautionary Statements ]:
P261-P280-P305 + P351 + P338-P310
[ Personal Protective Equipment ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
[ Hazard Codes ]:
C
[ Risk Phrases ]:
R34;R36/37
[ Safety Phrases ]:
S26;S27;S28;S45;S36/S37/S39
[ RIDADR ]:
UN 3265 8/PG 2
[ Packaging Group ]:
III
[ HS Code ]:
2932209090
Synthetic Route
Precursor & DownStream
Precursor
DownStream
Customs
[ HS Code ]: 2932209090
[ Summary ]:
2932209090. other lactones. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%
Articles
Org. Biomol. Chem. 7(7) , 1388-1396, (2009)
A two-step protocol for the synthesis of azepino[4,5-b]indolone derivatives featuring a xanthate radical oxidative aromatic substitution on the N-Boc protected tryptamine, using dilauroyl peroxide (DL...