Bis(triphenylphosphine)iminium chloride

Names

[ Name ]:
Bis(triphenylphosphine)iminium chloride

[Synonym ]:
MFCD00151523
1,1,1-Triphenyl-N-(triphenylphosphoranylidene)phosphoraniminium chloride
Phosphorus(1+), [(imino-κN)triphenylphosphoranato]triphenyl-, chloride (1:1)
1,1,1,3,3,3-Hexaphenyl-3l5-diphosphaz-2-en-1-ium chloride
PPNCI
ppncl
Bis(triphenylphosphoranylidene)ammonium chloride
HEXAPHENYLDIPHOSPHAZENIUM CHLORIDE
EINECS 244-170-6
1,1,1,3,3,3-Hexaphenyl-3λ-diphosphaz-2-en-1-ium chloride

Chemical & Physical Properties

[ Melting Point ]:
270-272 °C(lit.)

[ Molecular Formula ]:
C₃₆H₃₀ClNP₂

[ Molecular Weight ]:
574.031

[ Exact Mass ]:
573.154175

[ PSA ]:
35.76000

[ LogP ]:
7.76270

[ Storage condition ]:
2-8°C

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H332-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi,Xn

[ Risk Phrases ]:
R36/37/38:Irritating to eyes, respiratory system and skin . R20:Harmful by inhalation.

[ Safety Phrases ]:
S26-S36-S38-S36/37/39-S22

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ HS Code ]:
2931900090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

DownStream

Customs

[ HS Code ]: 2931900090

[ Summary ]:
2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%

Articles

Novel organic solvents for electrochemistry at the liquid/liquid interface.

Analyst 140(6) , 1947-54, (2015)

Two-phase voltammetry has been carried out using a reverse cell configuration, i.e. with the lower density organic solvent on the top of the aqueous solution in the cell, where the organic solvents co...

Cu nanoparticles electrodeposited at liquid-liquid interfaces: a highly efficient catalyst for the hydrogen evolution reaction.

Chemistry 21(12) , 4585-9, (2015)

The electrochemical deposition of Cu nanoparticles with an average diameter of approximately 25-35 nm has been reported at liquid-liquid interfaces by using the organic-phase electron-donor decamethyl...

A nitrate-selective electrode based on bis(triphenylphosphine)iminium salts.

Talanta 36 , 966-968, (1989)

A nitrate-sensitive electrode based on the ionic associates between bis(triphenylphosphine)iminium and nitrate ions in nitrobenzene solution is proposed. The electrode can be used for determinations o...