2-(2-Bromoethyl)-1,3-dioxolane

Names

[ Name ]:
2-(2-Bromoethyl)-1,3-dioxolane

[Synonym ]:
2-(2'-bromoethyl)-1,3-dioxolane
1-bromo-3-(1,3-dioxolane)-n-propane
2-(-bromoethyl)-1,3-dioxolane
2,7-DICHLOROFLUORENYL-4-ETHYLENE OXIDE
1,3-Dioxolane,2-(2-bromoethyl)
1-(1,3-dioxolan-2-yl)-2-bromoethane
3-Bromopropionaldehyde Ethylene Acetal
2-(1,3-dioxolan-2-yl)ethyl bromide
MFCD00003216
2-(2-Bromoethyl)-1,3-dioxolane
EINECS 242-551-1
1,3-Dioxolane, 2-(2-bromoethyl)-
2-(1,3-dioxa-2-cyclopentyl)-ethyl bromide

Chemical & Physical Properties

[ Density]:
1.5±0.1 g/cm3

[ Boiling Point ]:
200.9±15.0 °C at 760 mmHg

[ Molecular Formula ]:
C₅H₉BrO₂

[ Molecular Weight ]:
181.028

[ Flash Point ]:
85.0±0.0 °C

[ Exact Mass ]:
179.978592

[ PSA ]:
18.46000

[ LogP ]:
0.57

[ Vapour Pressure ]:
0.4±0.4 mmHg at 25°C

[ Index of Refraction ]:
1.473

[ Storage condition ]:
2-8°C

[ Water Solubility ]:
immiscible

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS06

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H301-H315-H319-H335

[ Precautionary Statements ]:
P261-P301 + P310-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xi:Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S37/39

[ RIDADR ]:
UN 2810 6.1/PG 3

[ WGK Germany ]:
2

[ HS Code ]:
2932999099

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

DownStream

Customs

[ HS Code ]: 2932999099

[ Summary ]:
2932999099. other heterocyclic compounds with oxygen hetero-atom(s) only. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

Articles

Suzuki-Miyaura cross-coupling of potassium dioxolanylethyltrifluoroborate and aryl/heteroaryl chlorides.

Org. Lett. 15(7) , 1536-9, (2013)

A robust and efficient protocol for the introduction of the dioxolanylethyl moiety onto various aryl and heteroaryl halides has been developed, providing cross-coupling yields up to 93%. Copper-cataly...

Facile syntheses for (5Z,9Z)-5,9-hexadecadienoic acid, (5Z,9Z)-5,9-nonadecadienoic acid, and (5Z,9Z)-5,9-eicosadienoic acid through a common synthetic route.

Chem. Phys. Lipids 100(1-2) , 33-40, (1999)

The delta 5,9 fatty acids (5Z,9Z)-5,9-hexadecadienoic acid, (5Z,9Z)-5,9-nonadecadienoic acid, and (5Z,9Z)-5,9-eicosadienoic acid were synthesized for the first time in four steps (9-12% overall yield)...

Tetrahedron Lett. 34 , 6411, (1993)