2-(2-Bromoethyl)-1,3-dioxane
Names
[ CAS No. ]:
33884-43-4
[ Name ]:
2-(2-Bromoethyl)-1,3-dioxane
[Synonym ]:
2-bromoethyl-1,3-dioxane
2,7-DICHLOROFLUORENYL BROMOMETHYL KETONE,OFF-WHITE SOLID
1,3-Dioxane, 2-(2-bromoethyl)-
3-Bromopropionaldehyde trimethylene acetal
EINECS 251-716-7
MFCD00006567
2-(2-Bromoethyl)-1,3-dioxane
2-(2-BROMOETHYL)-1,3-DIOXOLANE
Chemical & Physical Properties
[ Density]:
1.4±0.1 g/cm3
[ Boiling Point ]:
221.1±0.0 °C at 760 mmHg
[ Melting Point ]:
157-161 °C
[ Molecular Formula ]:
C6H11BrO2
[ Molecular Weight ]:
195.054
[ Flash Point ]:
96.7±0.0 °C
[ Exact Mass ]:
193.994232
[ PSA ]:
18.46000
[ LogP ]:
0.85
[ Vapour Pressure ]:
0.2±0.4 mmHg at 25°C
[ Index of Refraction ]:
1.468
[ Storage condition ]:
2-8°C
MSDS
Safety Information
[ Symbol ]:
GHS07
[ Signal Word ]:
Warning
[ Hazard Statements ]:
H315-H319-H335
[ Precautionary Statements ]:
P261-P305 + P351 + P338
[ Personal Protective Equipment ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
[ Hazard Codes ]:
Xi:Irritant;
[ Risk Phrases ]:
R36/37/38
[ Safety Phrases ]:
S26
[ RIDADR ]:
NONH for all modes of transport
[ WGK Germany ]:
3
[ HS Code ]:
2934999090
Synthetic Route
Customs
[ HS Code ]: 2934999090
[ Summary ]:
2934999090. other heterocyclic compounds. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%
Articles
Org. Biomol. Chem. 3(11) , 2109-13, (2005)
A new method for the asymmetric synthesis of 2-substituted pyrrolidines in three steps from commercially available starting materials is described. Addition of the Grignard reagent prepared from 2-(2-...
Use of triphenylmethyl (trityl) amino protecting group in the synthesis of ketomethylene analogues of peptides.Int. J. Pept. Protein Res. 23(6) , 581-90, (1984)
The Grignard reagents of 2-(2-bromoethyl)-1,3-dioxane and 2-(2-bromoethyl)-1,3-dioxolane readily reacted with the 2-thiopyridyl ester of N-triphenylmethyl-L-leucine to give the ketone adducts 2-[3-oxo...
J.C. StowellJ. Org. Chem. 41 , 560, (1976)