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2-(2-Bromoethyl)-1,3-dioxane

Names

[ CAS No. ]:
33884-43-4

[ Name ]:
2-(2-Bromoethyl)-1,3-dioxane

[Synonym ]:
2-bromoethyl-1,3-dioxane
2,7-DICHLOROFLUORENYL BROMOMETHYL KETONE,OFF-WHITE SOLID
1,3-Dioxane, 2-(2-bromoethyl)-
3-Bromopropionaldehyde trimethylene acetal
EINECS 251-716-7
MFCD00006567
2-(2-Bromoethyl)-1,3-dioxane
2-(2-BROMOETHYL)-1,3-DIOXOLANE

Chemical & Physical Properties

[ Density]:
1.4±0.1 g/cm3

[ Boiling Point ]:
221.1±0.0 °C at 760 mmHg

[ Melting Point ]:
157-161 °C

[ Molecular Formula ]:
C6H11BrO2

[ Molecular Weight ]:
195.054

[ Flash Point ]:
96.7±0.0 °C

[ Exact Mass ]:
193.994232

[ PSA ]:
18.46000

[ LogP ]:
0.85

[ Vapour Pressure ]:
0.2±0.4 mmHg at 25°C

[ Index of Refraction ]:
1.468

[ Storage condition ]:
2-8°C

MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xi:Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ HS Code ]:
2934999090

Synthetic Route

Customs

[ HS Code ]: 2934999090

[ Summary ]:
2934999090. other heterocyclic compounds. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

Articles

A rapid and general method for the asymmetric synthesis of 2-substituted pyrrolidines using tert-butanesulfinamide.

Org. Biomol. Chem. 3(11) , 2109-13, (2005)

A new method for the asymmetric synthesis of 2-substituted pyrrolidines in three steps from commercially available starting materials is described. Addition of the Grignard reagent prepared from 2-(2-...

Use of triphenylmethyl (trityl) amino protecting group in the synthesis of ketomethylene analogues of peptides.

Int. J. Pept. Protein Res. 23(6) , 581-90, (1984)

The Grignard reagents of 2-(2-bromoethyl)-1,3-dioxane and 2-(2-bromoethyl)-1,3-dioxolane readily reacted with the 2-thiopyridyl ester of N-triphenylmethyl-L-leucine to give the ketone adducts 2-[3-oxo...

J.C. Stowell

J. Org. Chem. 41 , 560, (1976)


More Articles


Related Compounds