1,4-Diaminoanthraquinone
Names
[ CAS No. ]:
128-95-0
[ Name ]:
1,4-Diaminoanthraquinone
[Synonym ]:
EINECS 204-922-6
1,4-Diaminoanthraquinone
MFCD00001224
1,4-Diaminoanthracene-9,10-dione
1,4-Diamino anthraquinone
9,10-Anthracenedione, 1,4-diamino-
1,4-Diamino-9,10-anthraquinone
Chemical & Physical Properties
[ Density]:
1.5±0.1 g/cm3
[ Boiling Point ]:
544.2±50.0 °C at 760 mmHg
[ Melting Point ]:
265-269 °C(lit.)
[ Molecular Formula ]:
C14H10N2O2
[ Molecular Weight ]:
238.241
[ Flash Point ]:
282.9±30.1 °C
[ Exact Mass ]:
238.074234
[ PSA ]:
86.18000
[ LogP ]:
2.98
[ Vapour Pressure ]:
0.0±1.5 mmHg at 25°C
[ Index of Refraction ]:
1.757
[ Storage condition ]:
Amber Vial, Refrigerator
MSDS
Toxicological Information
CHEMICAL IDENTIFICATION
- RTECS NUMBER :
- CB6300000
- CHEMICAL NAME :
- Anthraquinone, 1,4-diamino-
- CAS REGISTRY NUMBER :
- 128-95-0
- LAST UPDATED :
- 199710
- DATA ITEMS CITED :
- 10
- MOLECULAR FORMULA :
- C14-H10-N2-O2
- MOLECULAR WEIGHT :
- 238.26
- WISWESSER LINE NOTATION :
- L C666 BV IVJ DZ GZ
HEALTH HAZARD DATA
ACUTE TOXICITY DATA
- TYPE OF TEST :
- Standard Draize test
- ROUTE OF EXPOSURE :
- Administration into the eye
- SPECIES OBSERVED :
- Rodent - rabbit
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 5790 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Intraperitoneal
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 250 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
MUTATION DATA
- TYPE OF TEST :
- Mutation in microorganisms
- TEST SYSTEM :
- Microorganism - not otherwise specified
- DOSE/DURATION :
- 12800 ug/L
- REFERENCE :
- HEREAY Hereditas (Lund, Sweden). (Gjoerloffsgatan 121, S-261 34 Landskrona, Sweden) V.1- 1947- Volume(issue)/page/year: 99,209,1983 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - M2230 No. of Facilities: 245 (estimated) No. of Industries: 6 No. of Occupations: 12 No. of Employees: 3654 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - M2230 No. of Facilities: 78 (estimated) No. of Industries: 2 No. of Occupations: 6 No. of Employees: 2483 (estimated)
Safety Information
[ Personal Protective Equipment ]:
Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter
[ Hazard Codes ]:
Xi
[ Risk Phrases ]:
R22
[ Safety Phrases ]:
S22-S36/37
[ RIDADR ]:
NONH for all modes of transport
[ WGK Germany ]:
2
[ RTECS ]:
CB6300000
[ HS Code ]:
2922399090
Synthetic Route
Precursor & DownStream
Precursor
DownStream
Customs
[ HS Code ]: 2922399090
[ Summary ]:
2922399090 other amino-aldehydes, amino-ketones and amino-quinones, other than those containing more than one kind of oxygen function; salts thereof VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%
Articles
Inorg. Chem. 53(12) , 6082-93, (2014)
The compounds [(acac)2Ru(III)(μ-H2L(2-))Ru(III)(acac)2] (rac, 1, and meso, 1') and [(bpy)2Ru(II)(μ-H2L(•-))Ru(II)(bpy)2](ClO4)3 (meso, [2](ClO4)3) have been structurally, magnetically, spectroelectroc...
Vibrational analysis of 1,4-diaminoanthraquinone and 1,5-dichloroanthraquinone. A joint FTIR, FT-Raman and scaled quantum mechanical study.Spectrochim. Acta. A. Mol. Biomol. Spectrosc. 61(8) , 1799-809, (2005)
This work deals with the vibrational spectroscopy of 1,4-diaminoanthraquinone (1,4-DAAQ) and 1,5-dichloroanthraquinone (1,5-DCAQ). The mid and far FTIR and FT-Raman spectra were measured in the conden...
A new dark quencher for use in genetic analysis.Chem. Commun. (Camb.) (8) , 970-1, (2003)
A novel, long-wavelength, non-fluorescent quencher (LQ), based on 1,4-diaminoanthraquinone, has been incorporated at the 3' and 5'-termini of oligonucleotides. The quencher has been used in Molecular ...