Ammonium sulfide
Names
[ CAS No. ]:
12135-76-1
[ Name ]:
Ammonium sulfide
[Synonym ]:
Ammonium bisulfide
Ammoniumsulfid
AMMONIUM SULPHIDE
Ammonium Sulfide
trueammoniumsulfide
EINECS 235-223-4
FEMA 2053
NH4HS
diammoniumsulfide
ammonium sulfude
ammonium monosulfide
MFCD00010892
Chemical & Physical Properties
[ Density]:
1 g/mL at 25 °C
[ Boiling Point ]:
40 °C
[ Melting Point ]:
-18ºC
[ Molecular Formula ]:
H8N2S
[ Molecular Weight ]:
68.14190
[ Flash Point ]:
90 °F
[ Exact Mass ]:
68.04080
[ PSA ]:
31.78000
[ LogP ]:
0.76060
[ Index of Refraction ]:
n20/D 1.467
[ Stability ]:
Stable. Pure material is highly flammable - note wide explosion limits. Incompatible with strong oxidizing agents, strong acids, copper, brass, bronze, strong bases, zinc, aluminium.
MSDS
Safety Information
[ Symbol ]:
GHS02, GHS05, GHS09
[ Signal Word ]:
Danger
[ Hazard Statements ]:
H226-H314-H400
[ Supplemental HS ]:
Contact with acids liberates toxic gas.
[ Precautionary Statements ]:
P210-P260-P280-P303 + P361 + P353-P305 + P351 + P338-P370 + P378
[ Personal Protective Equipment ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
[ Hazard Codes ]:
F:Flammable;C:Corrosive;N:Dangerousfortheenvironment;
[ Risk Phrases ]:
R11;R31;R34;R50
[ Safety Phrases ]:
S26-S36/37/39-S45-S61
[ RIDADR ]:
UN 2683 8/PG 2
[ WGK Germany ]:
-
[ Packaging Group ]:
II
[ Hazard Class ]:
8
[ HS Code ]:
2830909000
Synthetic Route
Precursor & DownStream
Precursor
DownStream
Customs
[ HS Code ]: 2830909000
Articles
J. Agric. Food Chem. 47(1) , 245-8, (1999)
The reactions between 3-hydroxy-2-butanone and ammoniun sulfide at 25, 50, 75, 100, 125, and 150 degrees C were studied. Four well-known flavor compounds, 2,4,5-trimethyloxazole, 2,4, 5-trimethyl-3-ox...
A cataluminescence gas sensor for ammonium sulfide based on Fe(3)O(4)-carbon nanotubes composite.Luminescence 25(4) , 294-9, (2010)
In the present work, Fe(3)O(4)-carbon nanotubes (CNTs) composite was explored as a sensing material candidate for ammonium sulfide. Intense chemiluminescence emission can be observed during the cataly...
Visualization of iron in cultured macrophages: a cytochemical light and electron microscopic study using autometallography.Free Radic. Biol. Med. 15(1) , 1-11, (1993)
The objective of this study was to develop a sensitive cytochemical method for the visualization of iron, both at light microscopical (LM) and at electron microscopical (EM) levels, in glutaraldehyde-...