Tris(Trimethylsilyl) Phosphate
Names
[ CAS No. ]:
10497-05-9
[ Name ]:
Tris(Trimethylsilyl) Phosphate
[Synonym ]:
Phosphoric Acid Tris(trimethylsilyl) Ester
EINECS 234-028-1
Tris(trimethylsilyl) Phosphate
MFCD00008267
Chemical & Physical Properties
[ Density]:
0.945 g/mL at 25 °C(lit.)
[ Boiling Point ]:
228-229 °C720 mm Hg(lit.)
[ Melting Point ]:
3-4 °C(lit.)
[ Molecular Formula ]:
C9H27O4PSi3
[ Molecular Weight ]:
314.53900
[ Flash Point ]:
76 °F
[ Exact Mass ]:
314.09500
[ PSA ]:
54.57000
[ LogP ]:
4.64900
[ Vapour Pressure ]:
0.0977mmHg at 25°C
[ Index of Refraction ]:
n20/D 1.409(lit.)
MSDS
Toxicological Information
CHEMICAL IDENTIFICATION
- RTECS NUMBER :
- TC9700000
- CHEMICAL NAME :
- Phosphoric acid, tris(trimethylsilyl) ester
- CAS REGISTRY NUMBER :
- 10497-05-9
- BEILSTEIN REFERENCE NO. :
- 1794624
- LAST UPDATED :
- 199701
- DATA ITEMS CITED :
- 2
- MOLECULAR FORMULA :
- C9-H27-O4-P-Si3
- MOLECULAR WEIGHT :
- 314.60
- WISWESSER LINE NOTATION :
- 1-SI-1&1&-OPO&O-SI-1&1&1&O-SI-1&1&1
HEALTH HAZARD DATA
ACUTE TOXICITY DATA
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 3440 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- 85JCAE "Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J., Prague, Czechoslovakia, Avicenum, 1986 Volume(issue)/page/year: -,1233,1986
Safety Information
[ Symbol ]:
GHS02, GHS07
[ Signal Word ]:
Danger
[ Hazard Statements ]:
H225-H315-H319-H335
[ Precautionary Statements ]:
P210-P261-P305 + P351 + P338
[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
[ Hazard Codes ]:
F: Flammable;Xi: Irritant;
[ Risk Phrases ]:
R11
[ Safety Phrases ]:
S16-S26-S36
[ RIDADR ]:
UN 1993 3/PG 2
[ WGK Germany ]:
2
[ RTECS ]:
TC9700000
[ Packaging Group ]:
III
[ Hazard Class ]:
3.2
[ HS Code ]:
2931900090
Synthetic Route
Precursor & DownStream
Precursor
DownStream
Customs
[ HS Code ]: 2931900090
[ Summary ]:
2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%
Articles
Inorg. Chem. 41(25) , 6914-8, (2002)
A dealkylsilylation reaction between alumazene [2,6-(i-Pr)(2)C(6)H(3)NAlMe](3) (1) and tris(trimethylsilyl) ester of phosphoric acid (2) in a 1:3 molar ratio provides the heteroadamantane molecule (Me...
The use of [18O4]phosphoric acid in the quantitation of phosphate by gas-liquid chromatography-mass spectrometry analysis.Anal. Biochem. 107(2) , 324-31, (1980)
Tris (trimethylsilyl) phosphate: A film-forming additive for high voltage cathode material in lithium-ion batteries. Yan G, et al.
J. Power Sources 248 , 1306-11, (2014)