Organic Letters 2012-04-06

Cationic Pd(II)-catalyzed highly enantioselective arylative cyclization of alkyne-tethered enals or enones initiated by carbopalladation of alkynes with arylboronic acids.

Kun Shen, Xiuling Han, Xiyan Lu

Index: Org. Lett. 7th ed., 14 , 1756-1759, (2012)

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Abstract

Cationic Pd(II)-catalyzed enantioselective arylative cyclization of alkyne-tethered enals or enones initiated by carbopalladation of alkynes was developed without the necessity of a redox system.

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