Single-crystal to single-crystal phase transitions of bis (N-phenylisonicotinamide) silver (I) nitrate reveal cooperativity properties in porous molecular materials

…, AM Arif, F Cervantes-Lee, JC Noveron

Index: Mukherjee, Partha S.; Lopez, Nazario; Arif, Atta M.; Cervantes-Lee, Francisco; Noveron, Juan C. Chemical Communications, 2007 , # 14 p. 1433 - 1435

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Citation Number: 12

Abstract

Two single-crystal to single-crystal phase transitions in trans-[Ag (NPI) 2](NO3)· 2CH3OH (1a),(NPI= N-phenylisonicotinamide) were characterized with X-ray crystallography; the first transition is reversible and arises from a desolvation transition induced by vacuum and generated 1b; the second transition was induced by heat at 140° C and generated 1c.

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