Palladium??Catalyzed Aminocarbonylation of Aryl Chlorides at Atmospheric Pressure: The Dual Role of Sodium Phenoxide
…, DA Watson, RH Munday, SL Buchwald
Index: Martinelli, Joseph R.; Clark, Thomas P.; Watson, Donald A.; Munday, Rachel H.; Buchwald, Stephen L. Angewandte Chemie - International Edition, 2007 , vol. 46, # 44 p. 8460 - 8463
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Citation Number: 197
Abstract
Since Heck s seminal reports in 1974, palladium-catalyzed carbonylation has emerged as an indispensable method for the regioselective installation of carbonyl functional groups and remains an area of active research.[1, 2] Among the aryl halides, aryl chlorides are particularly attractive starting materials for these transformations, as they are both inexpensive and commercially abundant.[3] The relative chemical inertness of the aryl ...
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