Formation of Organomagnesium Compounds via EtMgBr-Mediated Radical Cyclization of Allyl β-Iodoacetals
A Inoue, H Shinokubo, K Oshima
Index: Inoue, Atsushi; Shinokubo, Hiroshi; Oshima, Koichiro Organic Letters, 2000 , vol. 2, # 5 p. 651 - 653
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Citation Number: 39
Abstract
Since the Grignard reagent was discovered in 1900, it has been widely used for the construction of organic molecules. It is the most basic and indispensable tool for organic chemists. 1 Grignard reagents have some common reaction patterns: (1) nucleophilic addition or substitution, (2) proton abstraction as a base, (3) magnesium−halogen exchange reactions. 2 There have been reports of some radical reactions using Grignard reagents in the presence or absence of a ...
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