Homolytic decomposition of t-alkyl 2, 2-dimethylperoxypropionates
T Komai, K Matsuyama, M Matsushima
Index: Komai, Takeshi; Matsuyama, Kazuo; Matsushima, Masaru Bulletin of the Chemical Society of Japan, 1988 , vol. 61, # 5 p. 1641 - 1646
Full Text: HTML
Citation Number: 13
Abstract
Decomposition rates and products of t-alkyl 2, 2-dimethylperoxypropionates were measured in cumene at several temperatures. The peroxyesters decomposed homolytically, depending on the structure of the t-alkyl moiety. The relative rates of the t-alkyl moieties to the 1, 1-dimethylethyl one were: 1, 1-dimethylbutyl (1.14), 1, 1-dimethylpropyl (1.19), 1, 1, 2- trimethylpropyl (1.85), 1, 1, 3, 3-tetramethylbutyl (2.10), and 1, 1-dimethyl-2-phenylethyl ( ...
Related Articles:
[Butlerow Justus Liebigs Annalen der Chemie, 1877 , vol. 189, p. 51]
[Brown,H.C.; Ravindranathan,M. Journal of the American Chemical Society, 1978 , vol. 100, # 6 p. 1865 - 1869]
Extremely efficient alkane oxidation by a new catalytic reagent H2O2/Os3 (CO) 12/pyridine
[Shul'Pin, Georgiy B.; Shilov, Alexander E.; Suess-Fink, Georg Tetrahedron Letters, 2001 , vol. 42, # 41 p. 7253 - 7256]
[Shul'pin, Georgiy B.; Kudinov, Aleksandr R.; Shul'pina, Lidia S.; Petrovskaya, Elena A. Journal of Organometallic Chemistry, 2006 , vol. 691, # 5 p. 837 - 845]
[Shul'pin, Georgiy B.; Golfeto, Camilla C.; Suess-Fink, Georg; Shul'pina, Lidia S.; Mandelli, Dalmo Tetrahedron Letters, 2005 , vol. 46, # 27 p. 4563 - 4567]