Stereospecific cross-coupling of vinyl halides with vinyl tin reagents catalyzed by palladium
JK Stille, BL Groh
Index: Stille,J.K.; Groh,B.L. Journal of the American Chemical Society, 1987 , vol. 109, p. 813
Full Text: HTML
Citation Number: 432
Abstract
Abstract: The palladium-catalyzed cross-coupling reaction of (E)-or (Z)-vinyl iodides with (E)- or (Z)-vinylstannanes gives good yields of stereoisomerically pure unsymmetrical dienes with the same double bond geometry as present in the coupling partners. The reaction takes place at ambient temperature in dimethylformamide in the presence of 1-2% bis (acetonitri1e) dichloropalladium. Because this reaction is tolerant of a variety of ...
Related Articles:
Stereospecific palladium-catalyzed coupling reactions of vinyl iodides with acetylenic tin reagents
[Stille,J.K.; Simpson,J.H. Journal of the American Chemical Society, 1987 , vol. 109, p. 2138]
[Khrimian, Ashot; Klun, Jerome A.; Hijji, Yousef; Baranchikov, Yuri N.; Pet'Ko, Vladimir M.; Mastro, Victor C.; Kramer, Matthew H. Journal of Agricultural and Food Chemistry, 2002 , vol. 50, # 22 p. 6366 - 6370]
[Tsuboi, Sadao; Ishii, Naomi; Sakai, Takashi; Tari, Isao; Utaka, Masanori Bulletin of the Chemical Society of Japan, 1990 , vol. 63, # 7 p. 1888 - 1893]
[Trost, Barry M.; Martin, Steven J. Journal of the American Chemical Society, 1984 , vol. 106, # 15 p. 4263 - 4265]
[Trost, Barry M.; Martin, Steven J. Journal of the American Chemical Society, 1984 , vol. 106, # 15 p. 4263 - 4265]