Oxidation of alcohols with electrolytic manganese dioxide. Its application for the synthesis of insect pheromones.
S Tsuboi, N Ishii, T Sakai, I Tari, M Utaka
Index: Tsuboi, Sadao; Ishii, Naomi; Sakai, Takashi; Tari, Isao; Utaka, Masanori Bulletin of the Chemical Society of Japan, 1990 , vol. 63, # 7 p. 1888 - 1893
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Citation Number: 16
Abstract
Oxidation of alcohols with electrolytic manganese dioxide under mild conditions afforded aldehydes and ketones in good yields. The method was applied for the syntheses of cystophorene [(3E, 5Z)-1, 3, 5-undecatriene](15) and a sex pheromone of forest tent cater pillar [(5Z, 7E)-5, 7-dodecadien-1-ol (18)].
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