Some chemistry of fluorinated octahedral sulfur compounds

T Kitazume, JM Shreeve

Index: Kitazume,T.; Shreeve,J.M. Journal of the American Chemical Society, 1978 , vol. 100, p. 492 - 496

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Citation Number: 25

Abstract

Abstract: Reactive nucleophiles such as C6FsSLi and CF3SLi readily attack cis-SF4 (OCF3) 2, SF5CI, CF3SF4C1, and cis-CF3SF4CF3 to form (RF)~ S~ and (RF)~ S~(RF= C6F5, CF3) plus CF20, RFSCI, CF3CI, and CF4, respectively. With CsFsLi, cis-SF4 (0CF3) 2 yields (C~ FS)~ SF~,(C6F5) 2SO, C6F6, and CF20; SFsCl gives (C~ FS)~ SO and C6Fs; CF3SF4CI forms (C6F5) 2s, C6F6, and CF3C1; and cis-CF3SF4CF3 produces CF3SF2CF3 and ...

Some perfluoroalkylsulfinyl halides. New preparations of trifluoromethylsulfur trifluoride

[Ratcliffe,C.T.; Shreeve,J.M. Journal of the American Chemical Society, 1968 , vol. 90, p. 5403 - 5408]

Aryl Fluoroalkyl Sulfides. I. Preparation by Reaction of Grignard Reagents with Trifluoromethanesulfenyl Chloride1

[Sheppard,W.A. Journal of Organic Chemistry, 1964 , vol. 29, p. 895 - 898]

639. Reactions of fluorocarbon radicals. Part XI. Synthesis and some reactions of trifluoromethanethiol and trifluoromethanesulphenyl chloride

[Haszeldine; Kidd Journal of the Chemical Society, 1953 , p. 3219,3225]