639. Reactions of fluorocarbon radicals. Part XI. Synthesis and some reactions of trifluoromethanethiol and trifluoromethanesulphenyl chloride
RN Haszeldine, JM Kidu
Index: Haszeldine; Kidd Journal of the Chemical Society, 1953 , p. 3219,3225
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Citation Number: 39
Abstract
CF,-S-SS* CF,+ CF,. SCF3+ CF,. S. SCF,+ CF,* S-CF,+ S The reaction of trifluoroiodomethane with sulphur is best carried out in an autoclave at 310, since the yield of bistrifluoromethyl disulpbide is then high (75y0), and the formation of carbon disulphide
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