Polyhedron

1D coordination polymers of silver (I) and copper (II) based on bis (N-heterocyclic carbene) ligands: Synthesis and structural studies

…, ZQ Wang, SW Liu, SS Ge, Y Zang, XG Wang, JH Guo

Index: Liu, Qing-Xiang; Shi, Meng-Chao; Wang, Zhi-Qiang; Liu, Shu-Wen; Ge, Shu-Sheng; Zang, Yan; Wang, Xiu-Guang; Guo, Jian-Hua Polyhedron, 2010 , vol. 29, # 10 p. 2121 - 2126

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Citation Number: 10

Abstract

The alkyl chain-linked diimidazolium (or dibenzimidazolium) salts, 1, 1′-diethyl-4, 4′- tetramethylene-diimidazolium-diiodide (L1H2· I2) and 1, 1′-diethyl-3, 3′-trimethylene- dibenzimidazolium-diiodide (L2H2· I2), and their silver (I) and copper (II) coordination polymers,[L1AgI] n (1) and [L2Cu2I4] n (2), have been prepared and characterized. Complex 1 is a 1D helical polymer generated by bidentated carbene ligands (L1) and Ag (I) atoms. ...

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