Photosubstitution of Dicyanobenzenes by Allylic Silanes, Germanes, and Stannanes via Photoinduced Electron Transfer.
K Nakanishi, K Mizuno, Y Otsuji
Index: Nakanishi, Kazuhisa; Mizuno, Kazuhiko; Otsuji, Yoshio Bulletin of the Chemical Society of Japan, 1993 , vol. 66, # 8 p. 2371 - 2379
Full Text: HTML
Citation Number: 45
Abstract
Photoreactions of 1, 2-and 1, 4-dicyanobenzenes (o-and p-DCB) with allylic silanes, germanes, and stannanes in acetonitrile were studied under various conditions. In these photoreactions, one of cyano groups of o-and p-DCB was replaced by allylic groups. With trimethyl (3-methyl-2-butenyl) silane,-germane, and-stannane, the photosubstitution occurred at both α-and γ-positions of the allylic moiety in a constant ratio, regardless of the ...
Related Articles:
[Julian, Lisa D.; Hartwig, John F. Journal of the American Chemical Society, 2010 , vol. 132, # 39 p. 13813 - 13822]
[Ikegami, Ryo; Koresawa, Akiko; Shibata, Takanori; Takagi, Kentaro Journal of Organic Chemistry, 2003 , vol. 68, # 6 p. 2195 - 2199]
[Gomes, Paulo; Gosmini, Corinne; Perichon, Jacques Journal of Organic Chemistry, 2003 , vol. 68, # 3 p. 1142 - 1145]
[Mizuno, Kazuhiko; Nakanishi, Kazuhisa; Otsuji, Yoshio Chemistry Letters, 1988 , p. 1833 - 1836]
Decarboxylative photosubstitution of dicyanobenzenes with aliphatic carboxylate ions
[Itou, Tatsuya; Yoshimi, Yasuharu; Morita, Toshio; Tokunaga, Yuji; Hatanaka, Minoru Tetrahedron, 2009 , vol. 65, # 1 p. 263 - 269]