Chemistry Letters

Photosubstitution of dicyanobenzenes by group 14 organometallic compounds via photoinduced electron-transfer. Additive and medium effects on photoinduced …

K Mizuno, K Nakanishi, Y Otsuji

Index: Mizuno, Kazuhiko; Nakanishi, Kazuhisa; Otsuji, Yoshio Chemistry Letters, 1988 , p. 1833 - 1836

Full Text: HTML

Citation Number: 4

Abstract

The phenanthrene-sensitized photoreaction of 1, 2-and 1, 4-dicyanobenzenes with group 14 organometallic compounds containing allylic and benzylic groups in CH 3 CN afforded the corresponding 2-and 4-allylated and-benzylated benzonitriles in high yields. These photoreactions were accelerated by the addition of Mg (CLO 4) 2 and benzene derivatives.

Related Articles:

Intramolecular hydroamination of unbiased and functionalized primary aminoalkenes catalyzed by a rhodium aminophosphine complex

[Julian, Lisa D.; Hartwig, John F. Journal of the American Chemical Society, 2010 , vol. 132, # 39 p. 13813 - 13822]

Functionalized arylzinc compounds in ethereal solvent: Direct synthesis from aryl iodides and zinc powder and application to Pd-catalyzed reaction with allylic halides

[Ikegami, Ryo; Koresawa, Akiko; Shibata, Takanori; Takagi, Kentaro Journal of Organic Chemistry, 2003 , vol. 68, # 6 p. 2195 - 2199]

Cobalt-catalyzed direct electrochemical cross-coupling between aryl or heteroaryl halides and allylic acetates or carbonates

[Gomes, Paulo; Gosmini, Corinne; Perichon, Jacques Journal of Organic Chemistry, 2003 , vol. 68, # 3 p. 1142 - 1145]

Photosubstitution of Dicyanobenzenes by Allylic Silanes, Germanes, and Stannanes via Photoinduced Electron Transfer.

[Nakanishi, Kazuhisa; Mizuno, Kazuhiko; Otsuji, Yoshio Bulletin of the Chemical Society of Japan, 1993 , vol. 66, # 8 p. 2371 - 2379]

Decarboxylative photosubstitution of dicyanobenzenes with aliphatic carboxylate ions

[Itou, Tatsuya; Yoshimi, Yasuharu; Morita, Toshio; Tokunaga, Yuji; Hatanaka, Minoru Tetrahedron, 2009 , vol. 65, # 1 p. 263 - 269]

More Articles...