Cobalt-catalyzed direct electrochemical cross-coupling between aryl or heteroaryl halides and allylic acetates or carbonates

P Gomes, C Gosmini, J Périchon

Index: Gomes, Paulo; Gosmini, Corinne; Perichon, Jacques Journal of Organic Chemistry, 2003 , vol. 68, # 3 p. 1142 - 1145

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Citation Number: 48

Abstract

The electroreduction of a mixture of functionalized aromatic or heteroaromatic bromides or chlorides and allylic compounds such as acetates or carbonates in an electrochemical cell fitted with a sacrificial iron anode affords, in the presence of cobalt halide associated with pyridine as ligand in acetonitrile or DMF, the corresponding coupling product in good yields.

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