2-Iodoxybenzenesulfonic acid as an extremely active catalyst for the selective oxidation of alcohols to aldehydes, ketones, carboxylic acids, and enones with oxone
M Uyanik, M Akakura, K Ishihara
Index: Uyanik, Muhammet; Akakura, Matsujiro; Ishihara, Kazuaki Journal of the American Chemical Society, 2009 , vol. 131, p. 251 - 262
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Citation Number: 180
Abstract
Electron-donating group-substituted 2-iodoxybenzoic acids (IBXs) such as 5-Me-IBX (1g), 5- MeO-IBX (1h), and 4, 5-Me2-IBX (1i) were superior to IBX 1a as catalysts for the oxidation of alcohols with Oxone (a trademark of DuPont) under nonaqueous conditions, although Oxone was almost insoluble in most organic solvents. The catalytic oxidation proceeded more rapidly and cleanly in nitromethane. Furthermore, 2-iodoxybenzenesulfonic acid ( ...
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