Scope and Mechanistic Studies of Catalytic Hydrosilylation with a High-Valent Nitridoruthenium (VI)
S Abbina, S Bian, C Oian, G Du
Index: Abbina, Srinivas; Bian, Shi; Oian, Casey; Du, Guodong ACS Catalysis, 2013 , vol. 3, # 4 p. 678 - 684
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Citation Number: 17
Abstract
Hydrosilylation catalyzed by a high-valent nitridoruthenium (VI) compound,[RuN (saldach)(CH3OH)]+[ClO4]−(1, where saldach is the dianion of racemic N, N′-cyclohexan- diyl-bis (salicylideneimine)) is described. Using phenylsilane as reductant, a variety of unsaturated organic substrates, including aldehydes, ketones, and imines, are effectively reduced to alcohols and amines, respectively, accompanied by the redistribution of ...
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