Indium metal as a reducing agent in organic synthesis

MR Pitts, JR Harrison, CJ Moody

Index: Pitts; Harrison; Moody Journal of the Chemical Society. Perkin Transactions 1, 2001 , # 9 p. 955 - 977

Full Text: HTML

Citation Number: 168

Abstract

The low first ionisation potential (5.8 eV) of indium coupled with its stability towards air and water, suggest that this metallic element should be a useful reducing agent for organic substrates. The use of indium metal for the reduction of CN bonds in imines, the heterocyclic ring in benzo-fused nitrogen heterocycles, of oximes, nitro compounds and conjugated alkenes and the removal of 4-nitrobenzyl protecting groups is described. Thus the ...

Related Articles:

Novel aldosterone synthase inhibitors with extended carbocyclic skeleton by a combined ligand-based and structure-based drug design approach

[Ono, Aoi; Suzuki, Nobuko; Kamimura, Junko Synthesis, 1987 , # 8 p. 736 - 738]

Palladium-catalyzed silane/siloxane reductions in the one-pot conversion of nitro compounds into their amines, hydroxylamines, amides, sulfonamides, and …

[Rahaim Jr., Ronald J.; Maleczka Jr., Robert E. Synthesis, 2006 , # 19 p. 3316 - 3340]

Preparation of copper nanoparticles and catalytic properties for the reduction of aromatic nitro compounds

[Duan, Zhongyu; Ma, Guoli; Zhang, Wenjun Bulletin of the Korean Chemical Society, 2012 , vol. 33, # 12 p. 4003 - 4006]

Chemoselective hydrogenation using molecular sieves-supported Pd catalysts: Pd/MS3A and Pd/MS5A

[Takahashi, Tohru; Yoshimura, Masatoshi; Suzuka, Hiroyasu; Maegawa, Tomohiro; Sawama, Yoshinari; Monguchi, Yasunari; Sajiki, Hironao Tetrahedron, 2012 , vol. 68, # 39 p. 8293 - 8299]

Copper/oxalohydrazide/ketone catalyzed synthesis of primary arylamines via coupling of aryl halides with aqueous ammonia in water

[Li, Ying; Zhu, Xinhai; Meng, Fei; Wan, Yiqian Tetrahedron, 2011 , vol. 67, # 30 p. 5450 - 5454]

More Articles...