Base??Catalyzed Cascade 1, 3??H Shift/Cyclization Reaction to Construct Polyaromatic Furans
YH Wang, H Liu, LL Zhu, XX Li…
Index: Wang, Ya-Hui; Liu, Heng; Zhu, Li-Li; Li, Xiao-Xiao; Chen, Zili Advanced Synthesis and Catalysis, 2011 , vol. 353, # 5 p. 707 - 712
Full Text: HTML
Citation Number: 8
Abstract
Abstract A convenient new method was developed to prepare unfused polyaromatic furan derivatives from diynyl-1, 6-diols through a novel base-catalyzed cascade 1, 3-H shift/cyclization process. Deuterium experiments were performed to determine that the 1, 3-H shift was the rate-determining step.
Related Articles:
[Matsuya, Yuji; Koiwai, Azusa; Minato, Daishiro; Sugimoto, Kenji; Toyooka, Naoki Tetrahedron Letters, 2012 , vol. 53, # 44 p. 5955 - 5957,3]
Lewis base-catalyzed alkynylation of carbonyl compounds with trimethylsilylacetylenes
[Kitazawa, Takayuki; Minowa, Tomofumi; Mukaiyama, Teruaki Chemistry Letters, 2006 , vol. 35, # 9 p. 1002 - 1003]
[Blanchard, Christiane; Vaultier, Michel; Mortier, Jacques Tetrahedron Letters, 1997 , vol. 38, # 51 p. 8863 - 8866]
Cobaltocene-Induced Low-Temperature Radical Coupling Reactions in a Cobalt–Alkyne Series
[Melikyan, Gagik G.; Rivas, Bianca; Harutyunyan, Stepan; Carlson, Louis; Sepanian, Ruth Organometallics, 2012 , vol. 31, # 5 p. 1653 - 1663]
Chemical Synthesis with Inductively Heated Copper Flow Reactors
[Ceylan, Sascha; Klande, Tobias; Vogt, Carla; Friese, Carsten; Kirschning, Andreas Synlett, 2010 , # 13 p. 2009 - 2013]