1, 4-and 1, 5-Diketones via palladium-catalyzed allylation of potassium enoxyborates

E Negishi, FT Luo, AJ Pecora…

Index: Negishi, Ei-ichi; Luo, Fen-Tair; Pecora Anthony J.; Silveira, Augustine Journal of Organic Chemistry, 1983 , vol. 48, # 14 p. 2427 - 2430

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Citation Number: 51

Abstract

(4) Martin, SF; Chou, TS Tetrahedron Lett. 1978, 1943.(5) Arzoumanian, H.; Metzger, JJ Organomet. Chem. 1973, 57, C1.(6) Mukaiyama, T.; Imamoto, T.; Kobayashi, S. Chem. Lett. 1973, 261. was 8745% on the basis of'H and 13C NMR examination. Since we have recently found that the regioselectivity in the conversion of 2-methylcyclohexanone into 4 or 5 is 95-98%,'the observed regioselectivity suggests that the regiospecificity in the ...

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