A facile synthesis of 2-acetonylcycloalkanones by using 2-(halomethyl)-3, 5-dioxahex-1-ene

XP Gu, Y Kirito, I Ikeda, M Okahara

Index: Gu, Xue-Ping; Kirito, Yoichi; Ikeda, Isao; Okahara, Mitsuo Journal of Organic Chemistry, 1990 , vol. 55, # 10 p. 3390 - 3393

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Citation Number: 5

Abstract

venient acetonylating reagent for various active protoncontaining During the investigation on the reactivity of la to extend its utility in organic synthesis, we have found that la could undergo a new type of 1, 3-migration of the methoxymethyl group in the presence of aluminum chloride to give 2-oxo-5-oxahexyl derivative^.^ Here, we report another useful reaction in which cycloalkanones were acetonylated easily by using la to afford 2- ...

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