Rh??Catalyzed Asymmetric Hydrogenation of Prochiral Olefins with a Dynamic Library of Chiral TROPOS Phosphorus Ligands

…, C Gennari, U Piarulli, JG de Vries…

Index: Monti, Chiara; Gennari, Cesare; Piarulli, Umberto; De Vries, Johannes G.; De Vries, Andre H. M.; Lefort, Laurent Chemistry - A European Journal, 2005 , vol. 11, # 22 p. 6701 - 6717

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Citation Number: 79

Abstract

Abstract A library of 19 chiral tropos phosphorus ligands, based on a flexible (tropos) biphenol unit and a chiral P-bound alcohol (11 phosphites) or secondary amine (8 phosphoramidites), was synthesized. These ligands were screened, individually and as a ...