Syntheses and properties of arenediazonium and anilinium cation lariat ether complexes: an “ostrich molecule” complex and evidence for intramolecular sidearm- …
JR Beadle, DM Dishong, RK Khanna, GW Gokel
Index: Beadle, James R.; Dishong, Dennis M.; Khanna, Raj K.; Gokel, George W. Tetrahedron, 1984 , vol. 40, # 20 p. 3935 - 3944
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Citation Number: 11
Abstract
The preparation of several novel lariat ethers (macrocyclic crown polyethers having sidearms bearing pendant donor groups) is reported, These compounds are ethers derived from known 2-hydroxymethyl-15-crown-5 or-21-crown-7. The sidearms Include 2- aminophenyl, 2, 4-diaminophenyl, 2-nitrophenyl, 2-(3'-nitrobiphenyl), and 2-(3'- aminobiphenyl). In several cases, the amino groups were converted into ammonium salts ...
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