Studies on the Efficient Generation of Phosphorus Carbon Bonds via a Rearrangement of PIII Esters Catalysed by Trimethylhalosilanes

…, S Olejniczak, M Cypryk, J Chojnowski…

Index: Dabkowski, Wojciech; Ozarek, Alfred; Olejniczak, Sebastian; Cypryk, Marek; Chojnowski, Julian; Michalski, Jan Chemistry - A European Journal, 2009 , vol. 15, # 7 p. 1747 - 1756

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Citation Number: 15

Abstract

Abstract Unprecedented C [BOND] P systems: Me 3 SiX (X= Br, I) catalyses rearrangements of P III esters R′ R′′ P [BOND] OR into the corresponding phosphoryl systems, providing a simple, mild and efficient route to a variety of structures containing P [BOND] C bonds. The mechanism has been found to be fundamentally different from that of the Arbuzov–Michaelis reaction and includes three definite steps a, b and c (see scheme).