Advanced Synthesis & Catalysis

The α??Chlorination of Aryl Methyl Ketones under Aerobic Oxidative Conditions

R Prebil, S Stavber

Index: Prebil, Rok; Stavber, Stojan Advanced Synthesis and Catalysis, 2014 , vol. 356, # 6 p. 1266 - 1274

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Citation Number: 6

Abstract

Abstract: The novel reaction system air/ammonium nitrate/iodine/hydrochloric acid [air/NH4NO3 (cat.)/I2 (cat.)/HCl] is introduced as a simple, safe, cheap, efficient and regioselective mediator for the α-chlorination of aryl, heteroaryl and alkyl methyl ketones