Organophosphorus redox systems

…, U Lechner-Knoblauch, P Haenel…

Index: Kaim, Wolfgang; Lechner-Knoblauch, Ulrike; Haenel, Peter; Bock, Hans Journal of Organic Chemistry, 1983 , vol. 48, p. 4206 - 4208

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Citation Number: 9

Abstract

Redox systems involving R, P-, R, P (X)-, and R, P+-substituted benzenes and biphenyls have been studied by cyclic voltammetry in dimethylformamide. The first one-electron reduction was found to be reversible in several instances, and stable radical anions, cations, and uncharged radicals were detected by high-resolution electron spin resonance. The second reduction step was found to be irreversible in all cases investigated. The ...