Journal of the American Chemical Society

Sulfones. I. Methods for the Preparation of Certain Alkanes, Alkenes, Acids and Lactones with Bis-(ethylsulfonyl)-methane1

MW Cronyn

Index: Cronyn Journal of the American Chemical Society, 1952 , vol. 74, p. 1225,1230

Full Text: HTML

Citation Number: 16

Abstract

A study of the potential value for synthetic purposes of bis-(alkylsulfonyl)-methanes has been initiated. Satisfactory conditions for the mono-and dialkylations of bis-(ethylsulfony1)- methane have been developed and several reactions of the dialkylated products are described. At 220'in cyclohexane over Raney nickel 5, 5-bis-(ethylsulfonyl)-2,~- dimethylnonane gives 5-ethylsulfonyl-2, 8-dimethylnonane (72%); while at 250', 2, 8- ...

 Related Synthetic Route
thf Structure

109-99-9

thf

5,5-bis-ethanesulfonyl-nonane Structure

408310-52-1

5,5-bis-ethanes...

~%

5-ethylidenenonane Structure

37549-88-5

5-ethylidenenonane

sodiodiethylsulphonylmethane Structure

34782-38-2

sodiodiethylsul...

2-Bromopropane Structure

75-26-3

2-Bromopropane

~%

Propane,1,1-bis(ethylsulfonyl)-2-methyl- Structure

6330-46-7

Propane,1,1-bis...

Bromocyclohexane Structure

108-85-0

Bromocyclohexane

~%

bis(ethylsulfonyl)methylcyclohexane Structure

6331-26-6

bis(ethylsulfon...

methyl iodide Structure

74-88-4

methyl iodide

~%

1-(1-ethylsulfonylethylsulfonyl)ethane Structure

32341-85-8

1-(1-ethylsulfo...

1,3-Dibromopropane Structure

109-64-8

1,3-Dibromopropane

~%

Cyclobutane,1,1-bis(ethylsulfonyl)- Structure

6330-45-6

Cyclobutane,1,1...

(2-Bromoethyl)benzene Structure

103-63-9

(2-Bromoethyl)b...

~%

Benzene,[3,3-bis(ethylsulfonyl)propyl]- Structure

6331-39-1

Benzene,[3,3-bi...

5,5-bis-ethanesulfonyl-2,8-dimethyl-nonane Structure

872802-58-9

5,5-bis-ethanes...

~%

2,8-dimethylnonane Structure

17302-30-6

2,8-dimethylnonane

1,1-bis-ethanesulfonyl-4-methyl-pentane Structure

411236-93-6

1,1-bis-ethanes...

~%

2,8-dimethylnonane Structure

17302-30-6

2,8-dimethylnonane

Isoamyl bromide Structure

107-82-4

Isoamyl bromide

~%

2,8-dimethylnonane Structure

17302-30-6

2,8-dimethylnonane

1-Bromooctadecane Structure

112-89-0

1-Bromooctadecane

~%

Nonadecane,1,1-bis(ethylsulfonyl)- Structure

6330-05-8

Nonadecane,1,1-...

sodiodiethylsulphonylmethane Structure

34782-38-2

sodiodiethylsul...

~%

1,1-bis(ethylsulfonyl)cyclopentane Structure

6331-13-1

1,1-bis(ethylsu...

1-Bromo-3-phenylpropane Structure

637-59-2

1-Bromo-3-pheny...

sodiodiethylsulphonylmethane Structure

34782-38-2

sodiodiethylsul...

~%

4,4-bis(ethylsulfonyl)butylbenzene Structure

6331-49-3

4,4-bis(ethylsu...

sodiodiethylsulphonylmethane Structure

34782-38-2

sodiodiethylsul...

(3-Chloropropyl)benzene Structure

104-52-9

(3-Chloropropyl...

~%

4,4-bis(ethylsulfonyl)butylbenzene Structure

6331-49-3

4,4-bis(ethylsu...

1-Bromobutane Structure

109-65-9

1-Bromobutane

sodiodiethylsulphonylmethane Structure

34782-38-2

sodiodiethylsul...

~%

1,1-bis(ethylsulfonyl)pentane Structure

7255-99-4

1,1-bis(ethylsu...

ALLYL CHLORIDE Structure

107-05-1

ALLYL CHLORIDE

~%

1-Butene,4,4-bis(ethylsulfonyl)- Structure

6330-44-5

1-Butene,4,4-bi...

sodiodiethylsulphonylmethane Structure

34782-38-2

sodiodiethylsul...

Benzyl chloride Structure

100-44-7

Benzyl chloride

~%

2,2-bis(ethylsulfonyl)ethylbenzene Structure

7144-96-9

2,2-bis(ethylsu...

2-Bromooctane Structure

557-35-7

2-Bromooctane

~%

1,1-bis(ethylsulfonyl)-2-methyl-octane Structure

6331-41-5

1,1-bis(ethylsu...


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