Fluoride-mediated boronic acid coupling reactions

…, DL Hageman, LD McClure

Index: Wright, Stephen W.; Hageman, David L.; McClure, Lester D. Journal of Organic Chemistry, 1994 , vol. 59, # 20 p. 6095 - 6097

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Citation Number: 334

Abstract

Discussion For our initial studies, we examined the reaction of phenylboric acid (1s) with methyl 4-bromophenylacetate (Ba). These reactants had provided only the saponified product 4-phenylphenylacetic acid when subjected to the palladium-catalyzed boronic acid coupling reaction in the presence of either sodium bicarbonate or sodium carbonate and had failed to afford any biaryl products with (1)(a) Suzuki, A.; Yanagi, T.; Miyaura, N. Synth. ...