Charge description of base-catalyzed alcoholysis of aryl phosphodiesters: a ribonuclease model

AM Davis, AD Hall, A Williams

Index: Journal of the American Chemical Society, , vol. 110, # 15 p. 5105 - 5108

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Citation Number: 88

Abstract

... Fission of the phosphodiester bond has considerable relevance with regard to the chemistry of nucleotides and ... This gives us the opportunity of measuring the calibrated charges on reacting oxygen atoms in ... 0002-7863/88/1510-5105~01.50/0 0 1988 American Chemical Society ...

 Related Synthetic Route
N/A Structure

115142-08-0

N/A

~%

2-Chloro-4-nitrophenol Structure

619-08-9

2-Chloro-4-nitr...

2',3'-cyclic UMP Structure

606-02-0

2',3'-cyclic UMP

N/A Structure

115142-07-9

N/A

~%

2',3'-cyclic UMP Structure

606-02-0

2',3'-cyclic UMP

2,4,5-Trichlorophenol Structure

95-95-4

2,4,5-Trichloro...

N/A Structure

115142-04-6

N/A

~%

3,5-Dichlorophenol Structure

591-35-5

3,5-Dichlorophenol

2',3'-cyclic UMP Structure

606-02-0

2',3'-cyclic UMP

uridine 3'-(2-chlorophenyl) phosphate Structure

115142-02-4

uridine 3'-(2-c...

~%

2-Chlorophenol Structure

95-57-8

2-Chlorophenol

2',3'-cyclic UMP Structure

606-02-0

2',3'-cyclic UMP

uridine 3'-(2,5-dichlorophenyl) phosphate Structure

115142-05-7

uridine 3'-(2,5...

~%

2,5-Dichlorophenol Structure

583-78-8

2,5-Dichlorophenol

2',3'-cyclic UMP Structure

606-02-0

2',3'-cyclic UMP

uridine 3'-(4-chlorophenyl) phosphate Structure

115142-01-3

uridine 3'-(4-c...

~%

2',3'-cyclic UMP Structure

606-02-0

2',3'-cyclic UMP

4-Chlorophenol Structure

106-48-9

4-Chlorophenol

(2R,3S,4R,5R)-5-(2,4-dioxo-3,4-dihydropyrimidin-1(2H)-yl)-4-hydroxy-2-(hydroxymethyl)tetrahydrofuran-3-yl (3-nitrophenyl) hydrogen phosphate Structure

115142-03-5

(2R,3S,4R,5R)-5...

~%

3-Nitrophenol Structure

554-84-7

3-Nitrophenol

2',3'-cyclic UMP Structure

606-02-0

2',3'-cyclic UMP


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