Gold (I)??Catalyzed Alkoxyhalogenation of β??Hydroxy?螃?, α??Difluoroynones

M Schuler, F Silva, C Bobbio, A Tessier…

Index: Schuler, Marie; Silva, Franck; Bobbio, Carla; Tessier, Arnaud; Gouverneur, Veronique Angewandte Chemie - International Edition, 2008 , vol. 47, # 41 p. 7927 - 7930

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Citation Number: 113

Abstract

The presence of fluorine substituents can significantly impact the physicochemical properties of organic compounds.[1] Novel methods for the preparation of fluorinated molecules based on fluorinated building blocks or CÀF bond forming reactions are therefore in great demand. New approaches to dihydro-or tetrahydropyranones featuring two or more fluorine substituents are valuable, as these compounds may be manipulated to enable, ...