Nickel-catalysed substitution reactions of allylic compounds with soft nucleophiles: an efficient alternative to palladium catalysis

H Bricout, JF Carpentier, A Mortreux

Index: Bricout, Herve; Carpentier, Jean-Francois; Mortreux, Andre Journal of the Chemical Society, Chemical Communications, 1995 , # 18 p. 1863 - 1864

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Citation Number: 2

Abstract

Substitution reactions of allyl alcohol derivatives 1a–c with diethylamine, phenol and dimethyl malonate are efficiently carried out in the presence of Ni (dppb) 2 (dppb= 1, 2- diphenylphosphinobutane) as catalyst and ammonium salts or bases as promoters or co- reagents.

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