Reaction of diazonium salts with transition metals. 8. Palladium-catalyzed carbon-carbon coupling of arenediazonium salts with organotin compounds

K Kikukawa, K Kono, F Wada…

Index: Kikukawa, Kiyoshi; Kono, Kiyoshi; Wada, Fumio; Matsuda, Tsutomu Journal of Organic Chemistry, 1983 , vol. 48, # 8 p. 1333 - 1336

Full Text: HTML

Citation Number: 92

Abstract

Arenediazonium salts are effectively functionalized with a methyl or vinyl group by palladium- catalyzed coupling with organotin compounds in acetonitrile at room temperature. Fairly good yields were obtained irrespective of the nature of a substituent on the aromatic ring, including a nitro group. Transformation of the diazonium group can proceed chemoselectively even in the presence of halogen substituents.